| 23. Journée | 05.02.2006 | AS Livorno | - | FC Messina | 2:2 | ||||
| 24. Journée | 08.02.2006 | Ascoli Calcio | - | AS Livorno | 0:0 | ||||
| 30. Journée | 18.03.2006 | AS Livorno | - | Juventus | 1:3 | ||||
| 31. Journée | 26.03.2006 | Empoli FC | - | AS Livorno | 2:1 | ||||
| 32. Journée | 02.04.2006 | Chievo Verona | - | AS Livorno | 2:1 | ||||
| 33. Journée | 08.04.2006 | AS Livorno | - | Udinese Calcio | 0:2 | ||||
| 34. Journée | 15.04.2006 | Lazio Roma | - | AS Livorno | 3:1 |  |
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| 37. Journée | 07.05.2006 | AS Livorno | - | Sampdoria | 0:0 | ||||
| 38. Journée | 14.05.2006 | AC Siena | - | AS Livorno | 0:0 |
Italie