| 4. Journée | 15.09.2012 | AS Livorno | - | Empoli FC | 4:2 | ||||
| 5. Journée | 22.09.2012 | Modena FC | - | AS Livorno | 1:0 | ||||
| 6. Journée | 25.09.2012 | AS Livorno | - | AS Cittadella | 2:2 | ||||
| 9. Journée | 14.10.2012 | Reggina Calcio | - | AS Livorno | 1:3 | ||||
| 14. Journée | 10.11.2012 | Ascoli Calcio | - | AS Livorno | 1:4 |  |
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| 17. Journée | 01.12.2012 | AS Livorno | - | US Grosseto FC | 4:0 | ||||
| 18. Journée | 08.12.2012 | Vicenza Calcio | - | AS Livorno | 3:3 | ||||
| 22. Journée | 30.12.2012 | AS Livorno | - | Juve Stabia | 2:2 | ||||
| 24. Journée | 02.02.2013 | AS Livorno | - | Pro Vercelli | 2:0 | ||||
| 26. Journée | 16.02.2013 | AS Livorno | - | Modena FC | 1:2 | ||||
| 27. Journée | 23.02.2013 | AS Cittadella | - | AS Livorno | 0:2 | ||||
| 29. Journée | 02.03.2013 | Spezia Calcio | - | AS Livorno | 1:2 | ||||
| 30. Journée | 09.03.2013 | AS Livorno | - | Reggina Calcio | 3:3 | ||||
| 41. Journée | 10.05.2013 | AS Livorno | - | Brescia Calcio | 3:0 | ||||
| 42. Journée | 18.05.2013 | Sassuolo Calcio | - | AS Livorno | 1:0 |  |
Italie