| 1er tour | 14.09.2006 | AS Livorno | - | FC Superfund | 2:0 | ||||
| 1er tour | 28.09.2006 | FC Superfund | - | AS Livorno | 0:1 | ||||
| Groupe A | 19.10.2006 | AS Livorno | - | Rangers FC | 2:3 |  |
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| Groupe A | 02.11.2006 | Partizan | - | AS Livorno | 1:1 | ||||
| Groupe A | 29.11.2006 | AS Livorno | - | Maccabi Haifa | 1:1 | ||||
| Groupe A | 14.12.2006 | AJ Auxerre | - | AS Livorno | 0:1 | ||||
| 3e tour | 14.02.2007 | AS Livorno | - | Espanyol Barcelona | 1:2 | ||||
| 3e tour | 22.02.2007 | Espanyol Barcelona | - | AS Livorno | 2:0 | |
Ghana