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| 25.09.2012 | 20:00 | AJ Auxerre | - | Angers SCO | 2:0 (1:0) | |
| 20:00 | SC Bastia | - | FC Metz | 3:0 (1:0) | ||
| 20:50 | Stade Rennais | - | AS Nancy Lorraine | 3:2 (2:1) | ||
| 26.09.2012 | 18:00 | Stade Brestois 29 | - | OGC Nice | 2:4 (1:3) | |
| 20:00 | AC Arles-Avignon | - | AC Ajaccio | 2:1 (0:0) | ||
| 20:55 | SM Caen | - | Toulouse FC | 0:1 (0:0) | ||
| 20:55 | AS Monaco | - | Valenciennes FC | 4:2 (2:2, 2:2) ap | ||
| 20:55 | FC Sochaux | - | Évian Thonon Gaillard | 3:2 (1:2, 2:2) ap | ||
| 20:55 | Stade de Reims | - | ESTAC Troyes | 1:2 (1:1) | ||
| 20:55 | FC Lorient | - | AS Saint-Étienne | 0:3 (1:0, 1:1, 1:1) tab |
