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| 21.01.2014 | 18:00 | AC Ajaccio | - | SM Caen | 0:2 (0:0) | |
| 18:30 | RC Lens | - | SC Bastia | 2:1 (0:0, 1:1) ap | ||
| 19:00 | Angers SCO | - | FC Sochaux | 1:0 (0:0) | ||
| 19:00 | US Boulogne | - | Stade Rennais | 0:2 (0:1) | ||
| 19:00 | FC Sète | - | Jura Sud | 2:0 (1:0) | ||
| 19:30 | IC Croix | - | Lille OSC | 0:3 (0:1) | ||
| 19:30 | US Concarneau | - | EA Guingamp | 2:3 (0:0, 1:1) ap | ||
| 20:00 | CA Bastia | - | Chamois Niortais | 5:4 (1:0, 2:2, 2:2) tab | ||
| 21:00 | Olympique Marseille | - | OGC Nice | 4:5 (2:3) | ||
| 22.01.2014 | 17:00 | Monts d'Or Azergues Foot | - | AS Monaco | 0:3 (0:1) | |
| 18:00 | Football Balagne Île-Rousse | - | Girondins Bordeaux | 4:3 (0:0, 0:0, 0:0) tab | ||
| 19:00 | AS Yzeure | - | Olympique Lyonnais | 1:3 (0:0) | ||
| 19:30 | AS Moulins | - | Toulouse FC | 2:1 (0:1) | ||
| 20:55 | Paris Saint-Germain | - | Montpellier HSC | 1:2 (1:1) | ||
| 23.01.2014 | 18:30 | AJ Auxerre | - | Dijon FCO | 3:2 (1:0, 2:2) ap | |
| 20:00 | AS Cannes | - | Stade Plabennec | 1:0 (1:0) |
