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| 14.04.1991 | Bilbao Athletic Club | - | Xerez CD | 0:0 | ||
| UE Figueres | - | Albacete | 3:1 | |||
| CE Sabadell | - | Sestao SC | 1:1 | |||
| Real Murcia | - | Palamós CF | 1:1 | |||
| Rayo Vallecano | - | RC Celta | 2:1 | |||
| UD Las Palmas | - | SD Eibar | 1:0 | |||
| Levante UD | - | UE Lleida | 2:0 | |||
| Elche CF | - | UD Salamanca | 0:0 | |||
| Deportivo La Coruña | - | CD Málaga | 1:0 | |||
| Real Avilés | - | Orihuela Deportiva CF | 1:1 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Murcia | 30 | 15 | 10 | 5 | 44:27 | 17 | 40:20 |
| 2 |
|
Deportivo La Coruña | 30 | 16 | 6 | 8 | 46:24 | 22 | 38:22 |
| 3 |
|
Albacete | 30 | 14 | 9 | 7 | 45:27 | 18 | 37:23 |
| 4 |
|
CD Málaga | 30 | 11 | 11 | 8 | 37:28 | 9 | 33:27 |
| 5 |
|
Orihuela Deportiva CF | 30 | 10 | 13 | 7 | 36:31 | 5 | 33:27 |
| 6 |
|
UE Figueres | 30 | 12 | 9 | 9 | 35:30 | 5 | 33:27 |
| 7 |
|
UE Lleida | 30 | 12 | 9 | 9 | 33:28 | 5 | 33:27 |
| 8 |
|
Sestao SC | 30 | 7 | 18 | 5 | 23:20 | 3 | 32:28 |
| 9 |
|
Real Avilés | 30 | 9 | 13 | 8 | 26:29 | -3 | 31:29 |
| 10 |
|
Rayo Vallecano | 30 | 7 | 16 | 7 | 34:35 | -1 | 30:30 |
| 11 |
|
SD Eibar | 30 | 7 | 15 | 8 | 26:26 | 0 | 29:31 |
| 12 |
|
Bilbao Athletic Club | 30 | 8 | 13 | 9 | 28:36 | -8 | 29:31 |
| 13 |
|
Elche CF | 30 | 10 | 8 | 12 | 32:33 | -1 | 28:32 |
| 14 |
|
RC Celta | 30 | 6 | 16 | 8 | 26:31 | -5 | 28:32 |
| 15 |
|
UD Salamanca | 30 | 8 | 11 | 11 | 33:28 | 5 | 27:33 |
| 16 |
|
CE Sabadell | 30 | 8 | 11 | 11 | 22:35 | -13 | 27:33 |
| 17 |
|
UD Las Palmas | 30 | 6 | 14 | 10 | 27:36 | -9 | 26:34 |
| 18 |
|
Palamós CF | 30 | 6 | 13 | 11 | 23:38 | -15 | 25:35 |
| 19 |
|
Xerez CD | 30 | 5 | 12 | 13 | 27:38 | -11 | 22:38 |
| 20 |
|
Levante UD | 30 | 3 | 13 | 14 | 17:40 | -23 | 19:41 |
