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| 14.11.1965 | UE Lleida | - | Burgos CF | 3:3 | ||
| Sporting Gijón | - | Barakaldo CF | 7:1 | |||
| Deportivo La Coruña | - | CA Osasuna | 4:0 | |||
| UP Langreo | - | CE L'Hospitalet | 4:2 | |||
| CE Europa | - | Racing Santander | 0:0 | |||
| CF Badalona | - | RC Celta | 2:1 | |||
| CD Condal | - | Real Oviedo | 1:3 | |||
| Real Sociedad | - | SD Indautxu | 4:1 | |||
| CD Badajoz | - | Algeciras CF | 1:2 | |||
| Cádiz CF | - | UD Melilla | 1:0 | |||
| Hércules CF | - | Real Valladolid | 3:3 | |||
| Real Murcia | - | CD Constància | 2:1 | |||
| Rayo Vallecano | - | Granada CF | 2:0 | |||
| Levante UD | - | CF Calvo Sotelo | 0:1 | |||
| CD Tenerife | - | CD Mestalla | 3:0 | |||
| CA Ceuta | - | Recreativo Huelva | 1:2 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| 1 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 9 | 7 | 1 | 1 | 19:6 | 13 | 15:3 |
| 2 |
|
Sporting Gijón | 9 | 6 | 2 | 1 | 23:10 | 13 | 14:4 |
| 3 |
|
Real Oviedo | 9 | 6 | 1 | 2 | 20:7 | 13 | 13:5 |
| 4 |
|
RC Celta | 9 | 6 | 0 | 3 | 18:10 | 8 | 12:6 |
| 5 |
|
CF Badalona | 9 | 5 | 1 | 3 | 9:10 | -1 | 11:7 |
| 6 |
|
Real Sociedad | 9 | 5 | 1 | 3 | 18:14 | 4 | 11:7 |
| 7 |
|
Burgos CF | 9 | 4 | 2 | 3 | 15:15 | 0 | 10:8 |
| 8 |
|
SD Indautxu | 9 | 4 | 1 | 4 | 14:16 | -2 | 9:9 |
| 9 |
|
CD Condal | 9 | 4 | 1 | 4 | 16:16 | 0 | 9:9 |
| 10 |
|
Racing Santander | 9 | 3 | 2 | 4 | 9:11 | -2 | 8:10 |
| 11 |
|
CA Osasuna | 9 | 3 | 1 | 5 | 8:14 | -6 | 7:11 |
| 12 |
|
CE Europa | 9 | 3 | 1 | 5 | 10:14 | -4 | 7:11 |
| 13 |
|
UE Lleida | 9 | 2 | 2 | 5 | 11:14 | -3 | 6:12 |
| 14 |
|
UP Langreo | 9 | 3 | 0 | 6 | 12:17 | -5 | 6:12 |
| 15 |
|
CE L'Hospitalet | 9 | 2 | 0 | 7 | 10:21 | -11 | 4:14 |
| 16 |
|
Barakaldo CF | 9 | 1 | 0 | 8 | 6:23 | -17 | 2:16 |
| 2 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Granada CF | 9 | 7 | 0 | 2 | 14:6 | 8 | 14:4 |
| 2 |
|
CF Calvo Sotelo | 9 | 6 | 1 | 2 | 13:8 | 5 | 13:5 |
| 3 |
|
Hércules CF | 9 | 4 | 3 | 2 | 13:9 | 4 | 11:7 |
| 4 |
|
CD Mestalla | 9 | 4 | 3 | 2 | 12:9 | 3 | 11:7 |
| 5 |
|
Levante UD | 9 | 4 | 2 | 3 | 14:6 | 8 | 10:8 |
| 6 |
|
Rayo Vallecano | 9 | 4 | 2 | 3 | 10:8 | 2 | 10:8 |
| 7 |
|
CD Tenerife | 9 | 5 | 0 | 4 | 19:7 | 12 | 10:8 |
| 8 |
|
CD Constància | 9 | 4 | 1 | 4 | 9:15 | -6 | 9:9 |
| 9 |
|
Real Valladolid | 9 | 2 | 5 | 2 | 12:14 | -2 | 9:9 |
| 10 |
|
Cádiz CF | 9 | 3 | 2 | 4 | 8:9 | -1 | 8:10 |
| 11 |
|
CA Ceuta | 9 | 3 | 2 | 4 | 10:14 | -4 | 8:10 |
| 12 |
|
Recreativo Huelva | 9 | 4 | 0 | 5 | 8:9 | -1 | 8:10 |
| 13 |
|
Algeciras CF | 9 | 3 | 1 | 5 | 7:7 | 0 | 7:11 |
| 14 |
|
Real Murcia | 9 | 3 | 1 | 5 | 6:10 | -4 | 7:11 |
| 15 |
|
CD Badajoz | 9 | 2 | 2 | 5 | 7:16 | -9 | 6:12 |
| 16 |
|
UD Melilla | 9 | 1 | 1 | 7 | 7:22 | -15 | 3:15 |
