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| 07.11.1965 | Racing Santander | - | Sporting Gijón | 0:0 | ||
| CA Osasuna | - | CF Badalona | 2:0 | |||
| Real Oviedo | - | UP Langreo | 2:0 | |||
| RC Celta | - | UE Lleida | 3:0 | |||
| Barakaldo CF | - | CD Condal | 0:2 | |||
| Burgos CF | - | Real Sociedad | 2:1 | |||
| SD Indautxu | - | CE Europa | 2:0 | |||
| CE L'Hospitalet | - | Deportivo La Coruña | 1:3 | |||
| Real Valladolid | - | CD Badajoz | 1:1 | |||
| Recreativo Huelva | - | Levante UD | 1:0 | |||
| Algeciras CF | - | Real Murcia | 0:0 | |||
| CF Calvo Sotelo | - | CD Tenerife | 2:1 | |||
| Granada CF | - | CA Ceuta | 2:0 | |||
| CD Mestalla | - | Cádiz CF | 1:0 | |||
| CD Constància | - | Rayo Vallecano | 3:0 | |||
| UD Melilla | - | Hércules CF | 1:2 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| 1 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 8 | 6 | 1 | 1 | 15:6 | 9 | 13:3 |
| 2 |
|
RC Celta | 8 | 6 | 0 | 2 | 17:8 | 9 | 12:4 |
| 3 |
|
Sporting Gijón | 8 | 5 | 2 | 1 | 16:9 | 7 | 12:4 |
| 4 |
|
Real Oviedo | 8 | 5 | 1 | 2 | 17:6 | 11 | 11:5 |
| 5 |
|
CF Badalona | 8 | 4 | 1 | 3 | 7:9 | -2 | 9:7 |
| 6 |
|
Burgos CF | 8 | 4 | 1 | 3 | 12:12 | 0 | 9:7 |
| 7 |
|
SD Indautxu | 8 | 4 | 1 | 3 | 13:12 | 1 | 9:7 |
| 8 |
|
CD Condal | 8 | 4 | 1 | 3 | 15:13 | 2 | 9:7 |
| 9 |
|
Real Sociedad | 8 | 4 | 1 | 3 | 14:13 | 1 | 9:7 |
| 10 |
|
Racing Santander | 8 | 3 | 1 | 4 | 9:11 | -2 | 7:9 |
| 11 |
|
CA Osasuna | 8 | 3 | 1 | 4 | 8:10 | -2 | 7:9 |
| 12 |
|
CE Europa | 8 | 3 | 0 | 5 | 10:14 | -4 | 6:10 |
| 13 |
|
UE Lleida | 8 | 2 | 1 | 5 | 8:11 | -3 | 5:11 |
| 14 |
|
CE L'Hospitalet | 8 | 2 | 0 | 6 | 8:17 | -9 | 4:12 |
| 15 |
|
UP Langreo | 8 | 2 | 0 | 6 | 8:15 | -7 | 4:12 |
| 16 |
|
Barakaldo CF | 8 | 1 | 0 | 7 | 5:16 | -11 | 2:14 |
| 2 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Granada CF | 8 | 7 | 0 | 1 | 14:4 | 10 | 14:2 |
| 2 |
|
CD Mestalla | 8 | 4 | 3 | 1 | 12:6 | 6 | 11:5 |
| 3 |
|
CF Calvo Sotelo | 8 | 5 | 1 | 2 | 12:8 | 4 | 11:5 |
| 4 |
|
Levante UD | 8 | 4 | 2 | 2 | 14:5 | 9 | 10:6 |
| 5 |
|
Hércules CF | 8 | 4 | 2 | 2 | 10:6 | 4 | 10:6 |
| 6 |
|
CD Constància | 8 | 4 | 1 | 3 | 8:13 | -5 | 9:7 |
| 7 |
|
Rayo Vallecano | 8 | 3 | 2 | 3 | 8:8 | 0 | 8:8 |
| 8 |
|
CA Ceuta | 8 | 3 | 2 | 3 | 9:12 | -3 | 8:8 |
| 9 |
|
Real Valladolid | 8 | 2 | 4 | 2 | 9:11 | -2 | 8:8 |
| 10 |
|
CD Tenerife | 8 | 4 | 0 | 4 | 16:7 | 9 | 8:8 |
| 11 |
|
Cádiz CF | 8 | 2 | 2 | 4 | 7:9 | -2 | 6:10 |
| 12 |
|
CD Badajoz | 8 | 2 | 2 | 4 | 6:14 | -8 | 6:10 |
| 13 |
|
Recreativo Huelva | 8 | 3 | 0 | 5 | 6:8 | -2 | 6:10 |
| 14 |
|
Algeciras CF | 8 | 2 | 1 | 5 | 5:6 | -1 | 5:11 |
| 15 |
|
Real Murcia | 8 | 2 | 1 | 5 | 4:9 | -5 | 5:11 |
| 16 |
|
UD Melilla | 8 | 1 | 1 | 6 | 7:21 | -14 | 3:13 |
