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| 26.09.1965 | Racing Santander | - | CF Badalona | 0:1 | ||
| Real Oviedo | - | CA Osasuna | 2:0 | |||
| Barakaldo CF | - | RC Celta | 2:1 | |||
| Burgos CF | - | UP Langreo | 2:0 | |||
| SD Indautxu | - | Deportivo La Coruña | 1:3 | |||
| CE Europa | - | Sporting Gijón | 1:3 | |||
| CE L'Hospitalet | - | UE Lleida | 2:1 | |||
| Real Sociedad | - | CD Condal | 2:1 | |||
| Real Valladolid | - | Levante UD | 1:1 | |||
| Cádiz CF | - | Real Murcia | 1:0 | |||
| Hércules CF | - | CD Badajoz | 3:0 | |||
| Algeciras CF | - | CF Calvo Sotelo | 2:0 | |||
| Granada CF | - | CD Tenerife | 2:1 | |||
| CD Mestalla | - | Rayo Vallecano | 2:1 | |||
| CD Constància | - | Recreativo Huelva | 1:0 | |||
| UD Melilla | - | CA Ceuta | 1:2 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| 1 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Sporting Gijón | 4 | 4 | 0 | 0 | 11:4 | 7 | 8:0 |
| 2 |
|
Real Sociedad | 4 | 3 | 1 | 0 | 8:4 | 4 | 7:1 |
| 3 |
|
Real Oviedo | 4 | 3 | 0 | 1 | 10:4 | 6 | 6:2 |
| 4 |
|
Deportivo La Coruña | 4 | 3 | 0 | 1 | 9:5 | 4 | 6:2 |
| 5 |
|
CF Badalona | 4 | 2 | 1 | 1 | 5:3 | 2 | 5:3 |
| 6 |
|
RC Celta | 4 | 2 | 0 | 2 | 7:6 | 1 | 4:4 |
| 7 |
|
CE L'Hospitalet | 4 | 2 | 0 | 2 | 6:8 | -2 | 4:4 |
| 8 |
|
Burgos CF | 4 | 2 | 0 | 2 | 5:5 | 0 | 4:4 |
| 9 |
|
SD Indautxu | 4 | 2 | 0 | 2 | 4:6 | -2 | 4:4 |
| 10 |
|
CD Condal | 4 | 2 | 0 | 2 | 5:6 | -1 | 4:4 |
| 11 |
|
Racing Santander | 4 | 2 | 0 | 2 | 5:4 | 1 | 4:4 |
| 12 |
|
UE Lleida | 4 | 1 | 0 | 3 | 5:5 | 0 | 2:6 |
| 13 |
|
Barakaldo CF | 4 | 1 | 0 | 3 | 3:8 | -5 | 2:6 |
| 14 |
|
CA Osasuna | 4 | 1 | 0 | 3 | 1:5 | -4 | 2:6 |
| 15 |
|
CE Europa | 4 | 1 | 0 | 3 | 3:8 | -5 | 2:6 |
| 16 |
|
UP Langreo | 4 | 0 | 0 | 4 | 1:7 | -6 | 0:8 |
| 2 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Granada CF | 4 | 4 | 0 | 0 | 9:2 | 7 | 8:0 |
| 2 |
|
Levante UD | 4 | 2 | 2 | 0 | 10:1 | 9 | 6:2 |
| 3 |
|
Hércules CF | 4 | 3 | 0 | 1 | 6:2 | 4 | 6:2 |
| 4 |
|
CF Calvo Sotelo | 4 | 3 | 0 | 1 | 9:5 | 4 | 6:2 |
| 5 |
|
CA Ceuta | 4 | 2 | 1 | 1 | 5:6 | -1 | 5:3 |
| 6 |
|
Rayo Vallecano | 4 | 2 | 0 | 2 | 5:3 | 2 | 4:4 |
| 7 |
|
Cádiz CF | 4 | 2 | 0 | 2 | 4:3 | 1 | 4:4 |
| 8 |
|
CD Mestalla | 4 | 1 | 2 | 1 | 5:6 | -1 | 4:4 |
| 9 |
|
CD Constància | 4 | 2 | 0 | 2 | 2:10 | -8 | 4:4 |
| 10 |
|
Real Murcia | 4 | 2 | 0 | 2 | 4:4 | 0 | 4:4 |
| 11 |
|
Recreativo Huelva | 4 | 2 | 0 | 2 | 5:3 | 2 | 4:4 |
| 12 |
|
Real Valladolid | 4 | 1 | 1 | 2 | 4:8 | -4 | 3:5 |
| 13 |
|
CD Badajoz | 4 | 1 | 0 | 3 | 2:8 | -6 | 2:6 |
| 14 |
|
Algeciras CF | 4 | 1 | 0 | 3 | 2:3 | -1 | 2:6 |
| 15 |
|
CD Tenerife | 4 | 1 | 0 | 3 | 8:4 | 4 | 2:6 |
| 16 |
|
UD Melilla | 4 | 0 | 0 | 4 | 3:15 | -12 | 0:8 |
