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| 06.03.1966 | Racing Santander | - | Burgos CF | 1:0 | ||
| UE Lleida | - | SD Indautxu | 1:1 | |||
| CA Osasuna | - | CD Condal | 2:1 | |||
| Real Oviedo | - | CE Europa | 3:0 | |||
| RC Celta | - | UP Langreo | 1:0 | |||
| Barakaldo CF | - | Real Sociedad | 2:2 | |||
| CF Badalona | - | Deportivo La Coruña | 0:1 | |||
| CE L'Hospitalet | - | Sporting Gijón | 4:3 | |||
| Real Valladolid | - | CD Mestalla | 1:0 | |||
| Levante UD | - | CA Ceuta | 1:0 | |||
| Recreativo Huelva | - | Real Murcia | 1:0 | |||
| CD Tenerife | - | UD Melilla | 1:2 | |||
| Algeciras CF | - | Cádiz CF | 0:2 | |||
| CF Calvo Sotelo | - | Rayo Vallecano | 1:1 | |||
| Granada CF | - | CD Badajoz | 3:0 | |||
| CD Constància | - | Hércules CF | 2:2 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| 1 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 26 | 15 | 6 | 5 | 41:16 | 25 | 36:16 |
| 2 |
|
RC Celta | 26 | 15 | 4 | 7 | 49:24 | 25 | 34:18 |
| 3 |
|
Sporting Gijón | 26 | 13 | 6 | 7 | 60:41 | 19 | 32:20 |
| 4 |
|
Real Oviedo | 26 | 13 | 6 | 7 | 36:18 | 18 | 32:20 |
| 5 |
|
CD Condal | 26 | 13 | 2 | 11 | 51:41 | 10 | 28:24 |
| 6 |
|
CA Osasuna | 26 | 12 | 4 | 10 | 34:35 | -1 | 28:24 |
| 7 |
|
UE Lleida | 26 | 9 | 8 | 9 | 35:30 | 5 | 26:26 |
| 8 |
|
Burgos CF | 26 | 11 | 4 | 11 | 35:38 | -3 | 26:26 |
| 9 |
|
Racing Santander | 26 | 9 | 8 | 9 | 34:37 | -3 | 26:26 |
| 10 |
|
Real Sociedad | 26 | 11 | 4 | 11 | 46:45 | 1 | 26:26 |
| 11 |
|
CF Badalona | 26 | 11 | 3 | 12 | 26:37 | -11 | 25:27 |
| 12 |
|
SD Indautxu | 26 | 11 | 3 | 12 | 39:44 | -5 | 25:27 |
| 13 |
|
UP Langreo | 26 | 10 | 2 | 14 | 37:51 | -14 | 22:30 |
| 14 |
|
CE Europa | 26 | 7 | 5 | 14 | 27:42 | -15 | 19:33 |
| 15 |
|
CE L'Hospitalet | 26 | 9 | 0 | 17 | 33:55 | -22 | 18:34 |
| 16 |
|
Barakaldo CF | 26 | 5 | 3 | 18 | 23:52 | -29 | 13:39 |
| 2 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Hércules CF | 26 | 14 | 6 | 6 | 39:22 | 17 | 34:18 |
| 2 |
|
CD Mestalla | 26 | 10 | 12 | 4 | 41:32 | 9 | 32:20 |
| 3 |
|
Granada CF | 26 | 13 | 5 | 8 | 34:27 | 7 | 31:21 |
| 4 |
|
Real Valladolid | 26 | 11 | 8 | 7 | 38:25 | 13 | 30:22 |
| 5 |
|
CD Tenerife | 26 | 12 | 6 | 8 | 38:23 | 15 | 30:22 |
| 6 |
|
Algeciras CF | 26 | 12 | 5 | 9 | 31:24 | 7 | 29:23 |
| 7 |
|
Rayo Vallecano | 26 | 11 | 6 | 9 | 32:22 | 10 | 28:24 |
| 8 |
|
CF Calvo Sotelo | 26 | 11 | 6 | 9 | 28:30 | -2 | 28:24 |
| 9 |
|
Levante UD | 26 | 9 | 8 | 9 | 33:22 | 11 | 26:26 |
| 10 |
|
Real Murcia | 26 | 10 | 5 | 11 | 23:25 | -2 | 25:27 |
| 11 |
|
Recreativo Huelva | 26 | 9 | 6 | 11 | 23:27 | -4 | 24:28 |
| 12 |
|
Cádiz CF | 26 | 8 | 7 | 11 | 21:25 | -4 | 23:29 |
| 13 |
|
CD Constància | 26 | 8 | 6 | 12 | 29:41 | -12 | 22:30 |
| 14 |
|
CA Ceuta | 26 | 9 | 2 | 15 | 28:41 | -13 | 20:32 |
| 15 |
|
UD Melilla | 26 | 6 | 6 | 14 | 20:43 | -23 | 18:34 |
| 16 |
|
CD Badajoz | 26 | 4 | 8 | 14 | 20:49 | -29 | 16:36 |
