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| 27.02.1966 | UE Lleida | - | CF Badalona | 1:0 | ||
| Sporting Gijón | - | Real Oviedo | 1:0 | |||
| Burgos CF | - | SD Indautxu | 2:1 | |||
| Deportivo La Coruña | - | RC Celta | 0:0 | |||
| UP Langreo | - | CA Osasuna | 2:2 | |||
| CE Europa | - | Barakaldo CF | 1:2 | |||
| CD Condal | - | CE L'Hospitalet | 2:0 | |||
| Real Sociedad | - | Racing Santander | 2:3 | |||
| CD Badajoz | - | CD Constància | 3:1 | |||
| Cádiz CF | - | Real Valladolid | 1:0 | |||
| Hércules CF | - | Algeciras CF | 2:2 | |||
| Real Murcia | - | Granada CF | 1:0 | |||
| Rayo Vallecano | - | Recreativo Huelva | 2:0 | |||
| CD Tenerife | - | Levante UD | 2:0 | |||
| CD Mestalla | - | UD Melilla | 1:1 | |||
| CA Ceuta | - | CF Calvo Sotelo | 1:0 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| 1 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 25 | 14 | 6 | 5 | 40:16 | 24 | 34:16 |
| 2 |
|
RC Celta | 25 | 14 | 4 | 7 | 48:24 | 24 | 32:18 |
| 3 |
|
Sporting Gijón | 25 | 13 | 6 | 6 | 57:37 | 20 | 32:18 |
| 4 |
|
Real Oviedo | 25 | 12 | 6 | 7 | 33:18 | 15 | 30:20 |
| 5 |
|
CD Condal | 25 | 13 | 2 | 10 | 50:39 | 11 | 28:22 |
| 6 |
|
Burgos CF | 25 | 11 | 4 | 10 | 35:37 | -2 | 26:24 |
| 7 |
|
CA Osasuna | 25 | 11 | 4 | 10 | 32:34 | -2 | 26:24 |
| 8 |
|
UE Lleida | 25 | 9 | 7 | 9 | 34:29 | 5 | 25:25 |
| 9 |
|
CF Badalona | 25 | 11 | 3 | 11 | 26:36 | -10 | 25:25 |
| 10 |
|
Real Sociedad | 25 | 11 | 3 | 11 | 44:43 | 1 | 25:25 |
| 11 |
|
SD Indautxu | 25 | 11 | 2 | 12 | 38:43 | -5 | 24:26 |
| 12 |
|
Racing Santander | 25 | 8 | 8 | 9 | 33:37 | -4 | 24:26 |
| 13 |
|
UP Langreo | 25 | 10 | 2 | 13 | 37:50 | -13 | 22:28 |
| 14 |
|
CE Europa | 25 | 7 | 5 | 13 | 27:39 | -12 | 19:31 |
| 15 |
|
CE L'Hospitalet | 25 | 8 | 0 | 17 | 29:52 | -23 | 16:34 |
| 16 |
|
Barakaldo CF | 25 | 5 | 2 | 18 | 21:50 | -29 | 12:38 |
| 2 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Hércules CF | 25 | 14 | 5 | 6 | 37:20 | 17 | 33:17 |
| 2 |
|
CD Mestalla | 25 | 10 | 12 | 3 | 41:31 | 10 | 32:18 |
| 3 |
|
CD Tenerife | 25 | 12 | 6 | 7 | 37:21 | 16 | 30:20 |
| 4 |
|
Granada CF | 25 | 12 | 5 | 8 | 31:27 | 4 | 29:21 |
| 5 |
|
Algeciras CF | 25 | 12 | 5 | 8 | 31:22 | 9 | 29:21 |
| 6 |
|
Real Valladolid | 25 | 10 | 8 | 7 | 37:25 | 12 | 28:22 |
| 7 |
|
Rayo Vallecano | 25 | 11 | 5 | 9 | 31:21 | 10 | 27:23 |
| 8 |
|
CF Calvo Sotelo | 25 | 11 | 5 | 9 | 27:29 | -2 | 27:23 |
| 9 |
|
Real Murcia | 25 | 10 | 5 | 10 | 23:24 | -1 | 25:25 |
| 10 |
|
Levante UD | 25 | 8 | 8 | 9 | 32:22 | 10 | 24:26 |
| 11 |
|
Recreativo Huelva | 25 | 8 | 6 | 11 | 22:27 | -5 | 22:28 |
| 12 |
|
Cádiz CF | 25 | 7 | 7 | 11 | 19:25 | -6 | 21:29 |
| 13 |
|
CD Constància | 25 | 8 | 5 | 12 | 27:39 | -12 | 21:29 |
| 14 |
|
CA Ceuta | 25 | 9 | 2 | 14 | 28:40 | -12 | 20:30 |
| 15 |
|
UD Melilla | 25 | 5 | 6 | 14 | 18:42 | -24 | 16:34 |
| 16 |
|
CD Badajoz | 25 | 4 | 8 | 13 | 20:46 | -26 | 16:34 |
