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| 20.02.1966 | Racing Santander | - | CE Europa | 1:1 | ||
| CA Osasuna | - | Deportivo La Coruña | 1:0 | |||
| Real Oviedo | - | CD Condal | 2:0 | |||
| RC Celta | - | CF Badalona | 3:0 | |||
| Barakaldo CF | - | Sporting Gijón | 2:3 | |||
| Burgos CF | - | UE Lleida | 1:0 | |||
| SD Indautxu | - | Real Sociedad | 2:0 | |||
| CE L'Hospitalet | - | UP Langreo | 2:1 | |||
| Real Valladolid | - | Hércules CF | 1:3 | |||
| Recreativo Huelva | - | CA Ceuta | 3:1 | |||
| Algeciras CF | - | CD Badajoz | 5:0 | |||
| CF Calvo Sotelo | - | Levante UD | 0:0 | |||
| Granada CF | - | Rayo Vallecano | 3:2 | |||
| CD Mestalla | - | CD Tenerife | 3:0 | |||
| CD Constància | - | Real Murcia | 0:1 | |||
| UD Melilla | - | Cádiz CF | 0:0 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| 1 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 24 | 14 | 5 | 5 | 40:16 | 24 | 33:15 |
| 2 |
|
RC Celta | 24 | 14 | 3 | 7 | 48:24 | 24 | 31:17 |
| 3 |
|
Sporting Gijón | 24 | 12 | 6 | 6 | 56:37 | 19 | 30:18 |
| 4 |
|
Real Oviedo | 24 | 12 | 6 | 6 | 33:17 | 16 | 30:18 |
| 5 |
|
CD Condal | 24 | 12 | 2 | 10 | 48:39 | 9 | 26:22 |
| 6 |
|
CF Badalona | 24 | 11 | 3 | 10 | 26:35 | -9 | 25:23 |
| 7 |
|
CA Osasuna | 24 | 11 | 3 | 10 | 30:32 | -2 | 25:23 |
| 8 |
|
Real Sociedad | 24 | 11 | 3 | 10 | 42:40 | 2 | 25:23 |
| 9 |
|
Burgos CF | 24 | 10 | 4 | 10 | 33:36 | -3 | 24:24 |
| 10 |
|
SD Indautxu | 24 | 11 | 2 | 11 | 37:41 | -4 | 24:24 |
| 11 |
|
UE Lleida | 24 | 8 | 7 | 9 | 33:29 | 4 | 23:25 |
| 12 |
|
Racing Santander | 24 | 7 | 8 | 9 | 30:35 | -5 | 22:26 |
| 13 |
|
UP Langreo | 24 | 10 | 1 | 13 | 35:48 | -13 | 21:27 |
| 14 |
|
CE Europa | 24 | 7 | 5 | 12 | 26:37 | -11 | 19:29 |
| 15 |
|
CE L'Hospitalet | 24 | 8 | 0 | 16 | 29:50 | -21 | 16:32 |
| 16 |
|
Barakaldo CF | 24 | 4 | 2 | 18 | 19:49 | -30 | 10:38 |
| 2 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Hércules CF | 24 | 14 | 4 | 6 | 35:18 | 17 | 32:16 |
| 2 |
|
CD Mestalla | 24 | 10 | 11 | 3 | 40:30 | 10 | 31:17 |
| 3 |
|
Granada CF | 24 | 12 | 5 | 7 | 31:26 | 5 | 29:19 |
| 4 |
|
Algeciras CF | 24 | 12 | 4 | 8 | 29:20 | 9 | 28:20 |
| 5 |
|
Real Valladolid | 24 | 10 | 8 | 6 | 37:24 | 13 | 28:20 |
| 6 |
|
CD Tenerife | 24 | 11 | 6 | 7 | 35:21 | 14 | 28:20 |
| 7 |
|
CF Calvo Sotelo | 24 | 11 | 5 | 8 | 27:28 | -1 | 27:21 |
| 8 |
|
Rayo Vallecano | 24 | 10 | 5 | 9 | 29:21 | 8 | 25:23 |
| 9 |
|
Levante UD | 24 | 8 | 8 | 8 | 32:20 | 12 | 24:24 |
| 10 |
|
Real Murcia | 24 | 9 | 5 | 10 | 22:24 | -2 | 23:25 |
| 11 |
|
Recreativo Huelva | 24 | 8 | 6 | 10 | 22:25 | -3 | 22:26 |
| 12 |
|
CD Constància | 24 | 8 | 5 | 11 | 26:36 | -10 | 21:27 |
| 13 |
|
Cádiz CF | 24 | 6 | 7 | 11 | 18:25 | -7 | 19:29 |
| 14 |
|
CA Ceuta | 24 | 8 | 2 | 14 | 27:40 | -13 | 18:30 |
| 15 |
|
UD Melilla | 24 | 5 | 5 | 14 | 17:41 | -24 | 15:33 |
| 16 |
|
CD Badajoz | 24 | 3 | 8 | 13 | 17:45 | -28 | 14:34 |
