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| 06.02.1966 | Racing Santander | - | CD Condal | 2:3 | ||
| UE Lleida | - | Real Sociedad | 2:1 | |||
| CA Osasuna | - | RC Celta | 4:1 | |||
| Real Oviedo | - | Deportivo La Coruña | 0:0 | |||
| Barakaldo CF | - | UP Langreo | 0:2 | |||
| Burgos CF | - | CE Europa | 1:1 | |||
| SD Indautxu | - | Sporting Gijón | 2:1 | |||
| CE L'Hospitalet | - | CF Badalona | 2:0 | |||
| Real Valladolid | - | Real Murcia | 1:0 | |||
| Recreativo Huelva | - | CF Calvo Sotelo | 1:0 | |||
| CD Tenerife | - | Cádiz CF | 1:0 | |||
| Algeciras CF | - | Rayo Vallecano | 1:0 | |||
| Granada CF | - | Levante UD | 1:0 | |||
| CD Mestalla | - | Hércules CF | 1:0 | |||
| CD Constància | - | CA Ceuta | 1:2 | |||
| UD Melilla | - | CD Badajoz | 1:0 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| 1 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 22 | 13 | 5 | 4 | 37:15 | 22 | 31:13 |
| 2 |
|
RC Celta | 22 | 13 | 3 | 6 | 45:23 | 22 | 29:15 |
| 3 |
|
Sporting Gijón | 22 | 11 | 5 | 6 | 50:32 | 18 | 27:17 |
| 4 |
|
Real Oviedo | 22 | 10 | 6 | 6 | 30:17 | 13 | 26:18 |
| 5 |
|
CD Condal | 22 | 11 | 2 | 9 | 45:36 | 9 | 24:20 |
| 6 |
|
CF Badalona | 22 | 10 | 3 | 9 | 25:32 | -7 | 23:21 |
| 7 |
|
CA Osasuna | 22 | 10 | 3 | 9 | 29:31 | -2 | 23:21 |
| 8 |
|
Real Sociedad | 22 | 10 | 3 | 9 | 40:38 | 2 | 23:21 |
| 9 |
|
Burgos CF | 22 | 9 | 4 | 9 | 32:34 | -2 | 22:22 |
| 10 |
|
UE Lleida | 22 | 7 | 7 | 8 | 32:28 | 4 | 21:23 |
| 11 |
|
UP Langreo | 22 | 10 | 1 | 11 | 34:45 | -11 | 21:23 |
| 12 |
|
SD Indautxu | 22 | 9 | 2 | 11 | 34:41 | -7 | 20:24 |
| 13 |
|
Racing Santander | 22 | 7 | 6 | 9 | 26:31 | -5 | 20:24 |
| 14 |
|
CE Europa | 22 | 7 | 4 | 11 | 25:35 | -10 | 18:26 |
| 15 |
|
CE L'Hospitalet | 22 | 7 | 0 | 15 | 27:46 | -19 | 14:30 |
| 16 |
|
Barakaldo CF | 22 | 4 | 2 | 16 | 16:43 | -27 | 10:34 |
| 2 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Hércules CF | 22 | 12 | 4 | 6 | 31:17 | 14 | 28:16 |
| 2 |
|
CD Mestalla | 22 | 9 | 10 | 3 | 36:29 | 7 | 28:16 |
| 3 |
|
Granada CF | 22 | 11 | 5 | 6 | 27:22 | 5 | 27:17 |
| 4 |
|
CD Tenerife | 22 | 11 | 5 | 6 | 34:17 | 17 | 27:17 |
| 5 |
|
Real Valladolid | 22 | 9 | 8 | 5 | 34:21 | 13 | 26:18 |
| 6 |
|
Algeciras CF | 22 | 11 | 3 | 8 | 23:19 | 4 | 25:19 |
| 7 |
|
CF Calvo Sotelo | 22 | 11 | 3 | 8 | 26:27 | -1 | 25:19 |
| 8 |
|
Rayo Vallecano | 22 | 9 | 5 | 8 | 24:17 | 7 | 23:21 |
| 9 |
|
Levante UD | 22 | 7 | 7 | 8 | 29:19 | 10 | 21:23 |
| 10 |
|
CD Constància | 22 | 8 | 5 | 9 | 25:32 | -7 | 21:23 |
| 11 |
|
Real Murcia | 22 | 8 | 4 | 10 | 20:23 | -3 | 20:24 |
| 12 |
|
Recreativo Huelva | 22 | 7 | 6 | 9 | 18:21 | -3 | 20:24 |
| 13 |
|
Cádiz CF | 22 | 6 | 5 | 11 | 17:24 | -7 | 17:27 |
| 14 |
|
CA Ceuta | 22 | 7 | 2 | 13 | 24:36 | -12 | 16:28 |
| 15 |
|
CD Badajoz | 22 | 3 | 8 | 11 | 17:38 | -21 | 14:30 |
| 16 |
|
UD Melilla | 22 | 5 | 4 | 13 | 17:40 | -23 | 14:30 |
