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| 23.01.1966 | Racing Santander | - | Deportivo La Coruña | 1:1 | ||
| Real Oviedo | - | RC Celta | 1:1 | |||
| Barakaldo CF | - | CF Badalona | 1:0 | |||
| Burgos CF | - | CD Condal | 3:0 | |||
| SD Indautxu | - | UP Langreo | 1:3 | |||
| CE Europa | - | UE Lleida | 3:2 | |||
| CE L'Hospitalet | - | CA Osasuna | 3:1 | |||
| Real Sociedad | - | Sporting Gijón | 2:2 | |||
| Real Valladolid | - | CA Ceuta | 4:0 | |||
| Cádiz CF | - | CD Badajoz | 0:0 | |||
| Hércules CF | - | CD Tenerife | 1:1 | |||
| Algeciras CF | - | Levante UD | 1:0 | |||
| Granada CF | - | Recreativo Huelva | 2:1 | |||
| CD Mestalla | - | Real Murcia | 1:1 | |||
| CD Constància | - | CF Calvo Sotelo | 5:1 | |||
| UD Melilla | - | Rayo Vallecano | 1:0 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| 1 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 20 | 12 | 4 | 4 | 36:15 | 21 | 28:12 |
| 2 |
|
RC Celta | 20 | 12 | 3 | 5 | 40:19 | 21 | 27:13 |
| 3 |
|
Sporting Gijón | 20 | 10 | 5 | 5 | 46:30 | 16 | 25:15 |
| 4 |
|
Real Oviedo | 20 | 10 | 5 | 5 | 30:16 | 14 | 25:15 |
| 5 |
|
Real Sociedad | 20 | 10 | 3 | 7 | 38:34 | 4 | 23:17 |
| 6 |
|
CF Badalona | 20 | 9 | 3 | 8 | 24:30 | -6 | 21:19 |
| 7 |
|
Burgos CF | 20 | 9 | 3 | 8 | 31:30 | 1 | 21:19 |
| 8 |
|
CD Condal | 20 | 9 | 2 | 9 | 41:34 | 7 | 20:20 |
| 9 |
|
CA Osasuna | 20 | 9 | 2 | 9 | 25:30 | -5 | 20:20 |
| 10 |
|
Racing Santander | 20 | 7 | 5 | 8 | 23:27 | -4 | 19:21 |
| 11 |
|
UE Lleida | 20 | 6 | 6 | 8 | 30:27 | 3 | 18:22 |
| 12 |
|
SD Indautxu | 20 | 8 | 2 | 10 | 32:39 | -7 | 18:22 |
| 13 |
|
UP Langreo | 20 | 9 | 0 | 11 | 31:44 | -13 | 18:22 |
| 14 |
|
CE Europa | 20 | 6 | 3 | 11 | 22:33 | -11 | 15:25 |
| 15 |
|
CE L'Hospitalet | 20 | 6 | 0 | 14 | 25:42 | -17 | 12:28 |
| 16 |
|
Barakaldo CF | 20 | 4 | 2 | 14 | 16:40 | -24 | 10:30 |
| 2 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Hércules CF | 20 | 11 | 4 | 5 | 29:16 | 13 | 26:14 |
| 2 |
|
CD Mestalla | 20 | 8 | 9 | 3 | 32:26 | 6 | 25:15 |
| 3 |
|
Granada CF | 20 | 10 | 5 | 5 | 26:20 | 6 | 25:15 |
| 4 |
|
CD Tenerife | 20 | 10 | 5 | 5 | 33:16 | 17 | 25:15 |
| 5 |
|
Real Valladolid | 20 | 8 | 8 | 4 | 33:20 | 13 | 24:16 |
| 6 |
|
Algeciras CF | 20 | 10 | 3 | 7 | 20:15 | 5 | 23:17 |
| 7 |
|
CF Calvo Sotelo | 20 | 10 | 3 | 7 | 24:26 | -2 | 23:17 |
| 8 |
|
Levante UD | 20 | 7 | 7 | 6 | 29:17 | 12 | 21:19 |
| 9 |
|
Rayo Vallecano | 20 | 8 | 5 | 7 | 23:16 | 7 | 21:19 |
| 10 |
|
CD Constància | 20 | 7 | 5 | 8 | 23:30 | -7 | 19:21 |
| 11 |
|
Real Murcia | 20 | 7 | 4 | 9 | 18:21 | -3 | 18:22 |
| 12 |
|
Cádiz CF | 20 | 6 | 5 | 9 | 17:21 | -4 | 17:23 |
| 13 |
|
Recreativo Huelva | 20 | 5 | 6 | 9 | 16:21 | -5 | 16:24 |
| 14 |
|
CD Badajoz | 20 | 3 | 7 | 10 | 14:34 | -20 | 13:27 |
| 15 |
|
CA Ceuta | 20 | 5 | 2 | 13 | 18:33 | -15 | 12:28 |
| 16 |
|
UD Melilla | 20 | 4 | 4 | 12 | 15:38 | -23 | 12:28 |
