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| 09.01.1966 | Racing Santander | - | RC Celta | 1:3 | ||
| UE Lleida | - | Sporting Gijón | 2:2 | |||
| Real Oviedo | - | CE L'Hospitalet | 2:1 | |||
| Barakaldo CF | - | CA Osasuna | 2:2 | |||
| Burgos CF | - | Deportivo La Coruña | 2:1 | |||
| SD Indautxu | - | CF Badalona | 4:0 | |||
| CE Europa | - | CD Condal | 0:0 | |||
| Real Sociedad | - | UP Langreo | 5:2 | |||
| Real Valladolid | - | CF Calvo Sotelo | 2:0 | |||
| Cádiz CF | - | Rayo Vallecano | 0:0 | |||
| Hércules CF | - | Real Murcia | 2:0 | |||
| CD Tenerife | - | CD Badajoz | 2:1 | |||
| Algeciras CF | - | Recreativo Huelva | 1:0 | |||
| CD Mestalla | - | CA Ceuta | 2:0 | |||
| CD Constància | - | Granada CF | 2:0 | |||
| UD Melilla | - | Levante UD | 2:1 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| 1 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 18 | 11 | 3 | 4 | 33:14 | 19 | 25:11 |
| 2 |
|
RC Celta | 18 | 11 | 2 | 5 | 36:18 | 18 | 24:12 |
| 3 |
|
Real Oviedo | 18 | 10 | 4 | 4 | 29:14 | 15 | 24:12 |
| 4 |
|
Sporting Gijón | 18 | 9 | 4 | 5 | 41:27 | 14 | 22:14 |
| 5 |
|
Real Sociedad | 18 | 10 | 2 | 6 | 35:28 | 7 | 22:14 |
| 6 |
|
CF Badalona | 18 | 8 | 3 | 7 | 21:29 | -8 | 19:17 |
| 7 |
|
Burgos CF | 18 | 8 | 3 | 7 | 28:28 | 0 | 19:17 |
| 8 |
|
SD Indautxu | 18 | 8 | 2 | 8 | 31:34 | -3 | 18:18 |
| 9 |
|
CD Condal | 18 | 8 | 2 | 8 | 37:30 | 7 | 18:18 |
| 10 |
|
Racing Santander | 18 | 7 | 4 | 7 | 22:23 | -1 | 18:18 |
| 11 |
|
CA Osasuna | 18 | 8 | 2 | 8 | 23:27 | -4 | 18:18 |
| 12 |
|
UE Lleida | 18 | 5 | 6 | 7 | 23:23 | 0 | 16:20 |
| 13 |
|
UP Langreo | 18 | 7 | 0 | 11 | 26:43 | -17 | 14:22 |
| 14 |
|
CE Europa | 18 | 5 | 3 | 10 | 18:28 | -10 | 13:23 |
| 15 |
|
CE L'Hospitalet | 18 | 5 | 0 | 13 | 21:36 | -15 | 10:26 |
| 16 |
|
Barakaldo CF | 18 | 3 | 2 | 13 | 15:37 | -22 | 8:28 |
| 2 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Hércules CF | 18 | 10 | 3 | 5 | 24:14 | 10 | 23:13 |
| 2 |
|
Granada CF | 18 | 9 | 5 | 4 | 24:17 | 7 | 23:13 |
| 3 |
|
CD Mestalla | 18 | 7 | 8 | 3 | 30:25 | 5 | 22:14 |
| 4 |
|
Real Valladolid | 18 | 7 | 8 | 3 | 28:17 | 11 | 22:14 |
| 5 |
|
CD Tenerife | 18 | 9 | 4 | 5 | 30:15 | 15 | 22:14 |
| 6 |
|
Rayo Vallecano | 18 | 8 | 5 | 5 | 23:14 | 9 | 21:15 |
| 7 |
|
Algeciras CF | 18 | 9 | 3 | 6 | 19:14 | 5 | 21:15 |
| 8 |
|
CF Calvo Sotelo | 18 | 9 | 3 | 6 | 22:21 | 1 | 21:15 |
| 9 |
|
Levante UD | 18 | 6 | 7 | 5 | 26:15 | 11 | 19:17 |
| 10 |
|
Real Murcia | 18 | 7 | 3 | 8 | 17:19 | -2 | 17:19 |
| 11 |
|
CD Constància | 18 | 6 | 4 | 8 | 18:29 | -11 | 16:20 |
| 12 |
|
Recreativo Huelva | 18 | 5 | 5 | 8 | 15:19 | -4 | 15:21 |
| 13 |
|
Cádiz CF | 18 | 5 | 4 | 9 | 16:21 | -5 | 14:22 |
| 14 |
|
CD Badajoz | 18 | 3 | 6 | 9 | 13:30 | -17 | 12:24 |
| 15 |
|
CA Ceuta | 18 | 4 | 2 | 12 | 15:29 | -14 | 10:26 |
| 16 |
|
UD Melilla | 18 | 3 | 4 | 11 | 14:35 | -21 | 10:26 |
