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| 17.01.2023 | 19:00 | Real Sociedad | - | RCD Mallorca | 1:0 (1:0) | |
| 21:00 | CD Alavés | - | Sevilla FC | 0:1 (0:0) | ||
| 18.01.2023 | 19:00 | Sporting Gijón | - | Valencia CF | 0:4 (0:3) | |
| 20:00 | Athletic Club | - | Espanyol Barcelona | 1:0 (1:0) | ||
| 21:00 | Levante UD | - | Atlético Madrid | 0:2 (0:0) | ||
| 21:00 | Real Betis | - | CA Osasuna | 2:4 (0:0, 1:1, 2:2) tab | ||
| 19.01.2023 | 20:00 | AD Ceuta FC | - | FC Barcelona | 0:5 (0:1) | |
| 21:00 | Villarreal CF | - | Real Madrid | 2:3 (2:0) |
