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| 03.01.2023 | 19:00 | CF La Nucía | - | Valencia CF | 0:3 (0:2) | |
| 19:00 | FC Cartagena | - | Villarreal CF | 1:5 (1:0) | ||
| 19:00 | Espanyol Barcelona | - | RC Celta | 3:1 (0:1, 1:1) ap | ||
| 21:00 | CP Cacereño | - | Real Madrid | 0:1 (0:0) | ||
| 21:00 | AD Ceuta FC | - | Elche CF | 1:0 (1:0) | ||
| 21:00 | Levante UD | - | Getafe CF | 3:2 (0:1) | ||
| 21:00 | Sporting Gijón | - | Rayo Vallecano | 2:0 (0:0) | ||
| 04.01.2023 | 19:00 | UD Logroñés | - | Real Sociedad | 0:1 (0:1) | |
| 19:00 | Pontevedra CF | - | RCD Mallorca | 0:2 (0:0, 0:0) ap | ||
| 19:00 | Linares Deportivo | - | Sevilla FC | 0:5 (0:2) | ||
| 20:00 | Real Oviedo | - | Atlético Madrid | 0:2 (0:1) | ||
| 21:00 | CF Intercity | - | FC Barcelona | 3:4 (0:1, 3:3) ap | ||
| 21:00 | CD Alavés | - | Real Valladolid | 1:0 (1:0) | ||
| 05.01.2023 | 16:00 | CD Ibiza | - | Real Betis | 1:4 (1:0) | |
| 16:00 | Gimnàstic de Tarragona | - | CA Osasuna | 1:2 (0:1, 1:1) ap | ||
| 21:00 | CD Eldense | - | Athletic Club | 1:6 (0:2) |
