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| 26.01.2021 | 19:00 | Real Valladolid | - | Levante UD | 2:4 (1:2) | |
| 21:00 | Girona FC | - | Villarreal CF | 0:1 (0:1) | ||
| 21:00 | Real Betis | - | Real Sociedad | 3:1 (0:1, 1:1) ap | ||
| 27.01.2021 | 19:00 | Sevilla FC | - | Valencia CF | 3:0 (3:0) | |
| 21:00 | Rayo Vallecano | - | FC Barcelona | 1:2 (0:0) | ||
| 21:00 | UD Almería | - | CA Osasuna | 5:4 (0:0, 0:0, 0:0) tab | ||
| 28.01.2021 | 19:00 | CDA Navalcarnero | - | Granada CF | 0:6 (0:4) | |
| 21:00 | CD Alcoyano | - | Athletic Club | 1:2 (1:0) |
