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| 05.11.2002 | 20:00 | Novelda CF | - | Terrassa FC | 0:3 (0:0) | |
| 20:00 | Hércules CF | - | RCD Mallorca | 3:4 (0:0, 0:0, 0:0) tab | ||
| 21:30 | Racing Ferrol | - | Deportivo La Coruña | 3:4 (1:1) | ||
| 06.11.2002 | 20:30 | Real Unión | - | Athletic Club | 2:1 (0:1) | |
| 20:30 | SD Eibar | - | CA Osasuna | 6:7 (0:0, 0:0, 0:0) tab | ||
| 20:30 | Palamós CF | - | Real Betis | 3:6 (2:1, 3:3) ap | ||
| 20:45 | Real Oviedo | - | Real Madrid | 0:4 (0:2) | ||
| 20:45 | Getafe CF | - | Real Valladolid | 1:2 (1:0, 1:1) ap | ||
| 21:00 | Cultural Leonesa | - | Atlético Madrid | 0:2 (0:0) | ||
| 21:00 | Xerez CD | - | Málaga CF | 2:0 (0:0) | ||
| 21:00 | Real Zaragoza | - | CD Alavés | 1:2 (0:2) | ||
| 21:15 | Real Murcia | - | CD Badajoz | 1:0 (1:0) | ||
| 21:30 | CD Linares | - | Sevilla FC | 1:2 (0:0) | ||
| 21:30 | UD Almería | - | Recreativo Huelva | 0:1 (0:0) | ||
| 21:45 | Alicante CF | - | Valencia CF | 5:4 (0:0, 1:1, 3:3) tab | ||
| 07.11.2002 | 21:30 | CD Numancia | - | RC Celta | 1:0 (1:0) |
