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| 08.11.2022 | 19:30 | RFC Seraing | - | Sporting Charleroi | 4:1 (0:1, 1:1) ap | |
| 20:00 | SK Deinze | - | KAS Eupen | 3:0 (2:0) | ||
| 20:30 | FCV Dender EH | - | Standard Liège | 0:1 (0:0) | ||
| 20:30 | Royal Francs Borains | - | Oud-Heverlee Leuven | 0:5 (0:2) | ||
| 09.11.2022 | 20:00 | Lommel SK | - | SV Zulte Waregem | 0:1 (0:0) | |
| 20:00 | Cercle Brugge | - | K Beerschot VA | 3:1 (1:1) | ||
| 20:00 | KVV THES Sport Tessenderlo | - | KV Oostende | 1:4 (0:0) | ||
| 20:00 | R. Cappellen FC | - | Union Saint-Gilloise | 1:7 (1:1) | ||
| 20:00 | KSC Lokeren-Temse | - | KV Mechelen | 0:5 (0:2) | ||
| 20:30 | KVC Westerlo | - | KRC Genk | 0:1 (0:1) | ||
| 20:30 | Sint-Truidense VV | - | RFC Meux | 1:0 (0:0) | ||
| 20:30 | KFC Dessel Sport | - | KAA Gent | 0:5 (0:4) | ||
| 20:45 | Patro Eisden MM | - | Club Brugge KV | 0:2 (0:0, 0:0) ap | ||
| 10.11.2022 | 20:00 | SK Beveren | - | Royal Antwerp FC | 2:4 (0:1, 2:2, 2:2) tab | |
| 20:00 | RWD Molenbeek | - | KV Kortrijk | 1:3 (0:0) | ||
| 20:45 | Lierse Kempenzonen | - | RSC Anderlecht | 8:9 (1:2, 2:2, 2:2) tab |
