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| 02.02.2021 | Rupel Boom FC | - | KAS Eupen | 0:5 | ||
| KVV THES Sport Tessenderlo | - | KRC Genk | 0:5 | |||
| KFC Dessel Sport | - | K Beerschot VA | 0:5 | |||
| 18:00 | Royal Antwerp FC | - | RAA La Louviére | 2:1 (1:0) | ||
| 18:00 | Union Saint-Gilloise | - | Royal Excel Mouscron | 2:1 (0:1) | ||
| 20:00 | Lommel SK | - | KV Kortrijk | 1:3 (0:1) | ||
| 03.02.2021 | 16:00 | KV Mechelen | - | RWD Molenbeek | 2:0 (1:0) | |
| 16:30 | Sporting Charleroi | - | KVC Westerlo | 1:0 (0:0) | ||
| 18:00 | KAA Gent | - | KSK Tongeren | 5:0 (2:0) | ||
| 18:00 | Oud-Heverlee Leuven | - | Cercle Brugge | 2:3 (1:2) | ||
| 19:00 | RFC Seraing | - | Standard Liège | 1:4 (0:2) | ||
| 19:30 | Club Brugge KV | - | Olsa Brakel | 6:1 (2:1) | ||
| 20:00 | KSC Lokeren-Temse | - | Sint-Truidense VV | 0:2 (0:1) | ||
| 20:00 | Waasland-Beveren | - | KV Oostende | 2:3 (1:1) | ||
| 20:00 | Olympic Charleroi | - | SV Zulte Waregem | 1:0 (0:0) | ||
| 21:15 | RFC Liège | - | RSC Anderlecht | 0:2 (0:1) |
