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| 24.09.2014 | 20:00 | KVV Coxyde | - | Royal Mouscron-Péruwelz | 4:3 (0:0, 0:0, 0:0) tab | |
| 20:00 | KFC Sp. Sint-Gillis-Waas | - | Cercle Brugge | 1:7 (0:3) | ||
| 20:00 | Olsa Brakel | - | KVC Westerlo | 6:1 (3:1) | ||
| 20:00 | KRC Genk | - | KRC Mechelen | 0:1 (0:0) | ||
| 20:00 | Sporting Lokeren | - | St. Eloois-Winkel Sport | 6:0 (4:0) | ||
| 20:30 | Sporting Charleroi | - | KAS Eupen | 2:0 (0:0) | ||
| 20:30 | KVW Zaventem | - | KV Oostende | 1:3 (1:3) | ||
| 20:30 | KFC Dessel Sport | - | KV Mechelen | 0:2 (0:2) | ||
| 20:30 | Oud-Heverlee Leuven | - | KV Kortrijk | 1:3 (0:1) | ||
| 20:30 | Club Brugge KV | - | Eendracht Aalst | 6:1 (2:0) | ||
| 20:30 | Lierse SK (old) | - | Sint-Truidense VV | 4:0 (0:0) | ||
| 20:30 | Patro Eisden MM | - | RSC Anderlecht | 3:5 (1:3, 3:3) ap | ||
| 20:30 | UR Namur | - | KAA Gent | 1:3 (0:2) | ||
| 20:30 | Lommel United | - | Waasland-Beveren | 2:1 (1:1) | ||
| 20:30 | KSK Heist | - | Standard Liège | 0:3 (0:2) | ||
| 20:45 | Royal Antwerp FC | - | SV Zulte Waregem | 0:4 (0:3) |
